I.Silviyati et al.
In addition to isotherm studies, the surface
chemistry of activated carbon plays a pivotal role
in adsorption mechanisms. Fourier Transform
Infrared Spectroscopy (FTIR) is employed to
identify surface functional groups responsible for
adsorptive interactions. FTIR detects specific
procedures. Data analysis was conducted using
statistical
tabulation
and
graphical
interpretation. The main variable studied was the
concentration of HCl used as an activating agent
in the production of activated carbon from
banana stem biomass. The activated carbon
preparation process comprised three primary
stages: dehydration, carbonization, and chemical
activation. The fixed parameters included a
vibrational
frequencies
associated
with
functional groups such as hydroxyl (–OH),
carbonyl (C=O), carboxyl (–COOH), and aromatic
C=C bonds [12]. These functional groups are
critical for the interaction with metal ions or
organic pollutants. FTIR spectra typically exhibit
absorption bands near 3400 cm⁻¹ (–OH), 1700
cm⁻¹ (C=O), and 1600 cm⁻¹ (C=C), which serve as
indicators of surface chemistry modifications
following activation or adsorption processes.
carbonization
temperature
of
400ꢀ°C,
a
carbonization duration of 1 hr, activation time of
4 hr, stirring speed of 400ꢀrpm, mesh size of 70,
and a contact time of 30 min between activated
carbon and Fe(II) solution.
The preparation of activated carbon involved the
following sequential stages: (1) Carbonization:
Pre-dried banana stem biomass was subjected to
pyrolysis at 400ꢀ°C for 1 hr in a muffle furnace. (2).
Chemical Activation: The resulting char was
impregnated with HCl at the designated
This study aims to synthesize HCl-activated
carbon from kepok banana stems, evaluate its
physicochemical properties based on national
standards, and investigate its adsorption
capacity for Fe(III) ions using Freundlich and
Langmuir isotherm models. The outcome is
expected to contribute to the development of
low-cost, sustainable adsorbents for water and
wastewater treatment applications.
concentrations and stirred for
4
hr. (3).
Neutralization and Washing: The activated
carbon was washed with distilled water until
neutral pH was achieved and then oven-dried.
(4). Adsorption Testing: The dried activated
carbon was exposed to 100ꢀppm Fe(II) solution
for 30 min to assess its adsorption performance.
Analytical technique: the physical and chemical
properties of the activated carbon were
evaluated based on the Indonesian National
Standard (SNI 06-3730-1995), including: moisture
content analysis [7], ash content analysis [13],
volatile matter content analysis [14], fixed carbon
content analysis [14], and iodine number
determination. The Fe(II) adsorption capacity was
Materials and Methods
Chemicals
The primary raw material used in this study was
kepok
banana
(Musa
paradisiaca)
stems,
collected from agricultural waste sources, Riau
Province. These stems were thoroughly cleaned,
sun-dried, and processed prior to further
treatment. The equipment utilized included a
mechanical grinder, porcelain crucibles, a muffle
furnace, desiccator, laboratory oven, burettes,
and a 70-mesh sieve. The chemicals employed in
the study were analytical grade and included
hydrochloric acid (HCl) at varying concentrations
(1.5ꢀN, 2.0ꢀN, 3.0ꢀN, 5.0ꢀN, and 7.0ꢀN), 0.1ꢀN iodine
solution, 0.1ꢀN sodium thiosulfate (Na₂S₂O₃), 1%
starch indicator, distilled water, and 100ꢀppm
measured
using
an
Atomic
Absorption
Spectrophotometer (AAS), while the surface
functional groups were characterized using
Fourier Transform Infrared (FTIR) spectroscopy
to identify active sites responsible for adsorption.
Activated Carbon
The preparation of activated carbon from Musa
paradisiaca (kepok banana) stems involved four
main stages: sample preparation, carbonization,
chemical activation, and neutralization. In the
first stage, the banana stems were thoroughly
washed with water to remove adhering soil and
impurities. The cleaned stems were then cut into
small segments to facilitate drying. The segments
Fe(II)
standard
solution
prepared
from
FeSO₄·7H₂O.
Preparation of Samples
The study employed an experimental approach,
incorporating both observational and analytical
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