Article  
Effectiveness of Kepok Banana (Musa paradisiaca) Bread-Based Adsorbent for  
Fe(III) Removal Using HCl Activation: Freundlich and Langmuir Isotherm Models  
Idha Silviyati *, Endang Supraptiah, Sri Murda Niati , Ibnu Hajar  
Aisyah Suci Ningsih, Feby Nia Amalda  
Chemical Engineering Department, Politeknik Negeri Sriwijaya, Palembang, Sumatera Selatan -30139,  
Indonesia  
Abstract  
Activated carbon can be synthesized from lignocellulosic biomass, such as kepok banana (Musa  
paradisiaca) stems, which are an abundant agricultural waste rich in cellulose (~64%). In this study, kepok  
banana stems were utilized as a precursor to produce activated carbon using hydrochloric acid (HCl) as  
the chemical activating agent. The activation process employed HCl concentrations of 1.5, 2.0, 3.0, 5.0,  
and 7.0 N, with a carbonization temperature of 400°C for 1 hr and an Fe adsorption contact time of 30  
minutes. The resulting activated carbon was evaluated based on its physicochemical properties  
according to the Indonesian National Standard (SNI 06-3730-1995). The sample treated with 3.0 N HCl  
showed optimal characteristics, including moisture content of 2.34%, ash content of 0.28%, volatile  
matter content of 2.05%, and fixed carbon content of 95.33%. Its iodine number reached 1116.98mg/g,  
and the Fe ion removal efficiency was 99.14%. FTIR spectroscopy confirmed the presence of functional  
groups typical of activated carbonOH, aromatic C=C, CH, and COsuggesting good adsorption  
potential. Furthermore, adsorption behavior was analyzed using the Freundlich isotherm model, which  
describes multilayer adsorption on heterogeneous surfaces. The findings demonstrate that activated  
carbon derived from kepok banana stems is an effective, low-cost, and environmentally friendly  
adsorbent for iron removal, suitable for applications in water purification and wastewater treatment.  
Keywords: Activated carbon; kepok banana stem; Iron (Fe)  
Graphical Abstract  
*
Corresponding author  
Received June 05th 2025; Accepted June 20th 2025; Available online June 30th 2025  
Copyright © 2025 by Authors, Published by Chempublish Journal. This is an open access article under the CC BY License  
130  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
(
)
V
C −C  
o
e
Introduction  
qe =  
(1)  
W
Activated carbon is a highly porous, amorphous  
form of carbon widely utilized as an adsorbent in  
purification, separation, and the removal of  
contaminants from liquids and gases due to its  
large surface area and high adsorption capacity  
[1,2]. It can be produced from various  
lignocellulosic biomass sources rich in cellulose,  
such as the stems of kepok banana (Musa  
paradisiaca), an abundant agricultural waste.  
These banana stems contain approximately 64%  
cellulose, along with hemicellulose (19%), lignin  
(5%), and water (11%) [3,4]. Their composition  
makes them a promising raw material for  
producing activated carbon, supporting both  
Notes:  
qe  
Co  
Ce  
V
= Adsorption capacity (mg/g)  
= Initial Fe concentration (mg/l)  
= Final Fe concentration (mg/l)  
= Sample volume (Liter)  
W
= Adsorbent weight (grams)  
1
= .퐶푒  
(2)  
Equation 2 can be derived linearly into equation  
3 [8].  
Log ()= log + 1 . log Ce  
(3)  
waste  
valorization  
and  
environmental  
sustainability.  
Tabel 1. Requirements for Activated Charcoal  
According to SNI No.06-3730-1995 [7]  
The activation process significantly influences the  
quality of activated carbon. Previous studies  
using sodium hydroxide (NaOH) as an activating  
agent yielded carbon with high ash content and  
low iodine adsorption, thus failing to meet the  
Indonesian National Standard (SNI 06-3730-  
1995). In contrast, hydrochloric acid (HCl)  
activation has been reported to produce better-  
Quality Parameter (%)  
Powder Quality  
Standard  
≤ 15 %  
Water Content  
Ash Content  
≤ 10 %  
Volatile Matter Content  
Bound Carbon Content  
Absorbency to Iodine  
Absorbency to Benzene  
≤ 25 %  
≥ 65 %  
≥ 750 mg/g  
≥ 25 %  
quality  
activated  
carbon  
with  
improved  
adsorption performance and reduced ash  
content, aligning with SNI requirements (Table 1)  
[5].  
The Langmuir isotherm, in contrast, assumes  
monolayer adsorption on homogeneous  
a
surface, with no interaction between adsorbed  
molecules. It is expressed as equation 4 [11].  
The Freundlich isotherm model is employed in  
this study to describe adsorption behavior,  
particularly the relationship between the  
adsorbed metal ion concentration and the  
equilibrium concentration in solution, assuming  
푏 . ꢂ . ꢃ  
qe = 푋  
=
(4)  
1+ꢂ . ꢃ  
Equation (4) can be reduced linearly to equation  
5 [8]  
a
heterogeneous  
surface  
with  
multilayer  
1
1
=
+
. 퐶푒  
(5)  
adsorption. This study aims to synthesize  
activated carbon from kepok banana stems using  
HCl activation, characterize its physicochemical  
properties, and evaluate its adsorption capacity  
for Fe(III) ions, particularly in the context of water  
and wastewater treatment applications.  
ꢂ . 푏  
Notes  
Ce  
= Equilibrium concentration of adsorbate  
in solution after adsorption (mg/L)  
= Amount of adsorbed adsorbate per  
adsorbent weight (mg/g)  
Q
Adsorption performance is often evaluated using  
isotherm models. The Freundlich isotherm  
k
b
= Adsorption equilibrium constant (L/mg)  
= Maximum adsorption capacity of the  
adsorbent (mg/g)  
describes  
multilayer  
adsorption  
on  
heterogeneous surfaces, where the adsorption  
capacity (qe) is related to the equilibrium  
concentration (Ce) by the empirical equation 1  
and 2 [9].  
1/kb  
1/b  
= Intercept  
= Slope  
131  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
In addition to isotherm studies, the surface  
chemistry of activated carbon plays a pivotal role  
in adsorption mechanisms. Fourier Transform  
Infrared Spectroscopy (FTIR) is employed to  
identify surface functional groups responsible for  
adsorptive interactions. FTIR detects specific  
procedures. Data analysis was conducted using  
statistical  
tabulation  
and  
graphical  
interpretation. The main variable studied was the  
concentration of HCl used as an activating agent  
in the production of activated carbon from  
banana stem biomass. The activated carbon  
preparation process comprised three primary  
stages: dehydration, carbonization, and chemical  
activation. The fixed parameters included a  
vibrational  
frequencies  
associated  
with  
functional groups such as hydroxyl (OH),  
carbonyl (C=O), carboxyl (COOH), and aromatic  
C=C bonds [12]. These functional groups are  
critical for the interaction with metal ions or  
organic pollutants. FTIR spectra typically exhibit  
absorption bands near 3400 cm¹ (OH), 1700  
cm¹ (C=O), and 1600 cm¹ (C=C), which serve as  
indicators of surface chemistry modifications  
following activation or adsorption processes.  
carbonization  
temperature  
of  
400°C,  
a
carbonization duration of 1 hr, activation time of  
4 hr, stirring speed of 400rpm, mesh size of 70,  
and a contact time of 30 min between activated  
carbon and Fe(II) solution.  
The preparation of activated carbon involved the  
following sequential stages: (1) Carbonization:  
Pre-dried banana stem biomass was subjected to  
pyrolysis at 400°C for 1 hr in a muffle furnace. (2).  
Chemical Activation: The resulting char was  
impregnated with HCl at the designated  
This study aims to synthesize HCl-activated  
carbon from kepok banana stems, evaluate its  
physicochemical properties based on national  
standards, and investigate its adsorption  
capacity for Fe(III) ions using Freundlich and  
Langmuir isotherm models. The outcome is  
expected to contribute to the development of  
low-cost, sustainable adsorbents for water and  
wastewater treatment applications.  
concentrations and stirred for  
4
hr. (3).  
Neutralization and Washing: The activated  
carbon was washed with distilled water until  
neutral pH was achieved and then oven-dried.  
(4). Adsorption Testing: The dried activated  
carbon was exposed to 100ppm Fe(II) solution  
for 30 min to assess its adsorption performance.  
Analytical technique: the physical and chemical  
properties of the activated carbon were  
evaluated based on the Indonesian National  
Standard (SNI 06-3730-1995), including: moisture  
content analysis [7], ash content analysis [13],  
volatile matter content analysis [14], fixed carbon  
content analysis [14], and iodine number  
determination. The Fe(II) adsorption capacity was  
Materials and Methods  
Chemicals  
The primary raw material used in this study was  
kepok  
banana  
(Musa  
paradisiaca)  
stems,  
collected from agricultural waste sources, Riau  
Province. These stems were thoroughly cleaned,  
sun-dried, and processed prior to further  
treatment. The equipment utilized included a  
mechanical grinder, porcelain crucibles, a muffle  
furnace, desiccator, laboratory oven, burettes,  
and a 70-mesh sieve. The chemicals employed in  
the study were analytical grade and included  
hydrochloric acid (HCl) at varying concentrations  
(1.5N, 2.0N, 3.0N, 5.0N, and 7.0N), 0.1N iodine  
solution, 0.1N sodium thiosulfate (NaSO), 1%  
starch indicator, distilled water, and 100ppm  
measured  
using  
an  
Atomic  
Absorption  
Spectrophotometer (AAS), while the surface  
functional groups were characterized using  
Fourier Transform Infrared (FTIR) spectroscopy  
to identify active sites responsible for adsorption.  
Activated Carbon  
The preparation of activated carbon from Musa  
paradisiaca (kepok banana) stems involved four  
main stages: sample preparation, carbonization,  
chemical activation, and neutralization. In the  
first stage, the banana stems were thoroughly  
washed with water to remove adhering soil and  
impurities. The cleaned stems were then cut into  
small segments to facilitate drying. The segments  
Fe(II)  
standard  
solution  
prepared  
from  
FeSO·7HO.  
Preparation of Samples  
The study employed an experimental approach,  
incorporating both observational and analytical  
132  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
were sun-dried for seven consecutive days to  
reduce moisture content, a crucial step to ensure  
efficient carbonization. The second stage was  
carbonization, wherein the dried biomass was  
weighed and subjected to pyrolysis in a muffle  
furnace at 400°C for 1 hr under limited oxygen  
conditions. The resulting biochar was ground  
using a mortar and sieved through a 70-mesh  
sieve to obtain a uniform particle size. The third  
stage was chemical activation. The sieved carbon  
was impregnated in hydrochloric acid (HCl) at  
various concentrations (0.1, 0.2, 0.5, 0.7, 1.0, 1.5,  
2.0, 3.0, 5.0, and 7.0 N). The mixture was stirred  
for 4 hr to allow sufficient activation. The final  
stage was neutralization, in which the activated  
carbon was washed repeatedly with distilled  
water until the rinse water reached neutral pH.  
The product was then dried in an oven at 110°C  
until a constant weight was achieved. After  
cooling in a desiccator, the activated carbon was  
ready for further analysis.  
Result and Discussion  
Characteristics of Activated Carbon from Kepok  
Banana Stems  
The physical and chemical characteristics of  
activated carbon derived from Kepok banana  
(Musa paradisiaca) stems treated with varying  
concentrations of hydrochloric acid (HCl) ranging  
from 1 N to 7 N are presented in Table 2. The  
water content of the samples varied between  
2.3392% and 3.5707%. Notably, the lowest  
moisture level was observed at a concentration  
of 3 N HCl, suggesting more effective drying and  
improved stability of the resulting activated  
carbon. A lower water content is advantageous  
because  
excess  
moisture  
can  
obstruct  
adsorption sites and diminish overall adsorption  
efficiency.  
The ash content exhibited a decreasing trend as  
the HCl concentration increased up to 3 N, where  
it reached a minimum value of 0.2799%. Ash  
represents the inorganic residues remaining  
after combustion and can negatively impact the  
adsorption process by occupying active sites.  
Therefore, the reduction in ash content at 3 N  
implies more efficient removal of mineral  
impurities and an enhancement in the chemical  
purity of the activated carbon.  
Metal Adsorption  
Adsorption performance was evaluated using a  
synthetic solution of Fe(II) prepared from  
FeSO·7HO. A total of 5 g of activated carbon  
(from each HCl concentration treatment) was  
added to 50mL of 100ppm Fe(II) solution. The  
mixture was stirred using a magnetic stirrer at  
400rpm for 30 min to ensure uniform contact.  
After the adsorption process, the solution was  
filtered, and the filtrate was collected for analysis.  
The residual Fe concentration was measured  
using an Atomic Absorption Spectrophotometer  
(AAS) to determine the adsorption efficiency  
Similarly, the volatile matter content showed a  
consistent  
decline  
with  
increasing  
acid  
concentration, achieving the lowest value of  
2.0502% at 3 N. Reduced volatile matter is  
indicative of a higher degree of carbonization and  
contributes to the development of a more stable  
and robust carbon structure, which is essential  
for maintaining adsorption capacity during  
repeated use. The bound carbon content  
increased progressively with acid concentration  
up to 3 N, attaining a maximum of 95.3307%. This  
finding suggests that a 3 N HCl treatment  
facilitates the optimal formation of the carbon  
matrix, thereby enhancing the structural integrity  
and adsorptive performance of the material.  
IR-Fingerprint  
To identify functional groups on the activated  
carbon surface, Fourier Transform Infrared  
Spectroscopy (FTIR) analysis was conducted.  
Approximately 0.1mg of dried activated carbon  
was finely ground using an agate mortar until  
homogeneous. The powder was evenly spread  
on the FTIR sample holder, ensuring full surface  
coverage. The sample was then scanned to  
record its infrared spectrum. Characteristic  
absorption peaks were analyzed to identify  
functional groups relevant to adsorption, such as  
OH, C=O, CH, and C=C.  
Moreover, the iodine absorbency, which serves  
as a key indicator of microporous surface area  
and porosity, also peaked at 3 N, recording a  
value of 1116.98 mg/g. High iodine numbers  
reflect a well-developed microporous network,  
133  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
which is crucial for effective adsorption of small  
molecules.  
matter, and superior iodine absorbency. These  
attributes collectively indicate that 3 N HCl  
constitutes the optimal activation condition for  
producing high-quality activated carbon from  
In summary, the activated carbon produced  
using 3 N HCl demonstrated the most favorable  
combination of physicochemical properties: high  
bound carbon content, minimal ash and volatile  
Kepok  
banana  
stems,  
offering  
promising  
potential for applications requiring efficient  
adsorbent materials.  
Tabel 2. Characteristic Test Data of Activated Carbon from Kepok Banana Stems  
Cons. HCl  
(N)  
Water  
Content (%)  
Ash  
Content (%)  
Volatile  
Matter  
Content (%)  
5.5505  
Bound Carbon  
Content (%)  
Absorbency  
Iod (mg/g)  
1
1.5  
2
3
5
3.5707  
3.0194  
2.7575  
2.3392  
2.9094  
3.3177  
2.3607  
0.4103  
0.3299  
0.2799  
0.8695  
1.3082  
88.118  
92.9592  
93.384  
95.3307  
93.3117  
91.5064  
1002.75  
1078.91  
1104.29  
1116.98  
1015.44  
951.975  
3.6111  
3.5286  
2.0502  
2.9094  
7
3.8677  
Tabel 3. Data on Iron (Fe) Metal Absorption Results  
HCl Concentration  
(N)  
Initial Concentration  
(ppm)  
Final Concentration  
(ppm)  
Adsorbed Fe  
Content (%)  
1
1.5  
2
3
5
1.7619  
1.6667  
1.0952  
0.8571  
1.0476  
1.4762  
98.2373  
98.3325  
98.9043  
99.1425  
98.9519  
98.5231  
99.9524  
7
N HCl concentration, the ash content produced  
increased to 0.8695%. High ash content can  
reduce the adsorption power of activated carbon  
on adsorbates because of the many metal oxides  
and minerals that spread and cover the pores of  
activated carbon. Based on the data obtained  
from the ash content test, all activated carbon  
products meet the SNI 06-3730-1995 standard,  
which is less than 10%.  
12  
10  
8
6
4
2
0
0
2
4
6
8
HCl Activator Concentration(N)  
SNI (%)  
Ash Content  
The  
relationship  
between  
HCl  
activator  
Figure 1. Effect of HCl Activator Concentration on  
concentration and ash content can be seen in  
Figure 2. In Figure 2, it can be seen that the ash  
content value decreases with the addition of  
activator concentration. Activated carbon that  
Water Content  
In Figure 1, it can be seen that the ash content  
value decreases with the addition of activator  
concentration. Activated carbon that has the best  
concentration is the 3 N concentration of  
0.2799%. The higher the concentration of HCl  
activator used, the smaller the ash content. At 5  
has the best concentration is the  
3
N
concentration of 0.2799%. The higher the  
concentration of HCl activator used, the smaller  
the ash content. At 5 N HCl concentration, the  
resulting ash content increased to 0.8695%. High  
134  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
ash content can reduce the adsorption power of  
activated carbon on adsorbates due to the large  
amount of metal oxides and minerals that spread  
and cover the pores of activated carbon. Based  
on the data obtained from the ash content test,  
all activated carbon products meet the SNI 06-  
3730-1995 standard, which is less than 10%.  
Bound Carbon Content  
120  
100  
80  
60  
40  
20  
0
12  
10  
8
0
2
4
6
8
HCl Activator Concentration (N)  
SNI (%)  
Figure 4. Effect of HCl Activator Concentration on  
6
Bound Carbon Content  
4
2
Based on Figure 4, it can be seen that the  
percentage of bound carbon content tends to  
increase with each addition of HCl activator,  
namely at concentrations of 1.5 ; 2 and 3 N. The  
increase in percentage is influenced by the low  
value of moisture content, ash content, and  
volatile substance content of activated carbon.  
Based on the bound carbon content of all  
samples, it has met the quality standards of  
activated carbon, which is at least 65% with  
concentrations of 1.5 ; 2 ; 3 ; 5 N and 7 N because  
the banana stem carbonization time is almost  
perfect and the carbonization temperature is set  
according to the condition of the banana stem as  
raw material.  
0
0
2
4
6
8
HCl Activator Concentration (N)  
SNI (%)  
Figure 2. Effect of HCl Activator Concentration on  
Ash Content  
Volatile Matter Content Test. The relationship  
between HCl activator concentration and  
moisture content can be seen in Figure 3.  
30  
20  
10  
0
Iodine Absorbency. The relationship between HCl  
activator concentration and iodine absorbance  
can be seen in Figure 5.  
0
2
4
6
8
HCl Activator Concentration (N)  
SNI  
1200  
1000  
800  
600  
400  
200  
0
Figure 3. Effect of HCl Activator Concentration on  
Volatile Matter Content  
Figure 3 shows that the volatile matter content  
decreased  
with  
increasing  
HCl  
activator  
concentration. The vaporized substance content  
decreased from 0.1 N concentration to 3 N  
concentration. The lowest vaporized substance  
content at 3 N activator concentration was  
2.0502%. The level of vaporized substances  
increased at a concentration of 5 N, which  
amounted to 2.9094%. The increase in ash  
content occurs because of the many metal oxides  
and minerals that spread and cover the pores of  
activated carbon. The volatile matter content of  
all samples has met the SNI 06-3730-1995  
standard, which is no more than 25%.  
0
2
4
6
8
HCl Activator Concentration (N)  
SNI (mg/g)  
Figure 5. Effect of HCl Activator Concentration  
on Iodine Absorbency  
135  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
The percentage of iodine absorption increased  
with each addition of HCl concentration, namely  
1.5; 2 and 3 N concentrations, but decreased at 5  
N and 7 N HCl concentrations. This is because the  
(0.8571 ppm) and highest Fe removal efficiency  
(99.1425%) occurred with activated carbon  
treated at 3 N HCl, again highlighting its superior  
performance.  
All treatments achieved  
Fe  
higher  
the  
addition  
of  
the  
activator  
adsorption efficiencies above 98%, indicating  
that even non-optimized activated carbon  
exhibits strong Fe adsorption capacity.  
concentration, the greater the effect of the  
activator in binding the residual compounds to  
exit through the charcoal micro pores, so that  
there is a decrease with too high a concentration  
of NaOH which results in too fast a mass transfer  
of the activator binding the remaining tar to exit  
the charcoal micro pores so that the remnants of  
tar collect on the surface of the charcoal micro  
pores, as a result the adsorption power of  
activated charcoal decreases [17]. Based on all  
the iodine absorption sample data, all samples  
meet the SNI 06-3730-1995 standard, which is a  
minimum of 750 mg/g.  
Adsorption efficiency increased with acid  
concentration up to  
3
N, consistent with  
improvements in iodine number and carbon  
content. Beyond 3 N (e.g., 5 N and 7 N),  
performance declined slightly, likely due to pore  
collapse or over-etching, which can reduce  
effective surface area. There is a clear correlation  
between bound carbon content, iodine number,  
and Fe adsorption efficiency. Higher bound  
carbon and iodine numbers reflect more  
developed porous structures, enabling more  
effective trapping of metal ions.  
Iron (Fe) Metal Absorption Efficiency  
Table 3 presents the data on Fe(III) adsorption  
from solution using the produced activated  
carbon. Initial Fe concentration was 99.9524 ppm  
across all tests. The lowest final Fe concentration  
The consistent peak performance at 3 N HCl  
across both tables suggests this concentration  
yields optimal textural and chemical properties  
for metal adsorption applications.  
Figure 8. Graphic Isoterm Freundlich Fe  
is seen in the Freundlich isotherm graph, this  
proves that the adsorption isotherm in the  
research of making activated carbon from kepok  
banana stems follows the Freundlich isotherm  
model. The n value describes the adsorption  
Isoterm Adsorption  
From Figures 8 and 9, it can be seen that the  
regression value that shows a number close to 1  
136  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
process, where  
n
<
1
indicates chemical  
in the adsorption process, the smaller the 1/n  
value, the stronger the interaction between the  
adsorbent and the adsorbate [19-20].  
adsorption, n = 1 indicates linear adsorption, and  
n > 1 indicates physical adsorption [17]. The 1/n  
value is a function of the strength of adsorption  
Figure 9. Graphic Isoterm Langmuir Fe  
determine the chemical components of activated  
carbon in the form of functional groups and  
active groups of activated carbon. The resulting  
infrared spectra are as in Figure 10.  
IR In this study, the adsorbent of activated kepok  
banana stem carbon was identified using FTIR  
(Fourier  
Transform  
Infrared  
Spectroscopy)  
(Genesys 20 Visible Spectrophotometer, USA) to  
Figure 10. IR Fingerprint activated carbon  
From the test sample, bread of kapok banana  
after being activated, the FTIR spectrum shows  
distinct peaks indicating the presence of various  
functional groups. The activated carbon displays  
a high-intensity peak at 3236.08 cm¹, which  
corresponds to O-H stretching vibrations,  
typically from hydroxyl groups found in alcohols  
or phenols. This indicates surface oxidation and  
functionalization, which commonly occurs during  
the activation process [21-23].  
137  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
In comparison, non-activated carbon generally  
shows much weaker or broader O-H stretching  
bands due to the limited surface functional  
groups and lower porosity. The emergence of a  
sharp O-H band in activated samples confirms  
enhanced surface chemistry, favorable for  
adsorptive interactions [24-26].  
generally  
enhances  
the  
physicochemical  
properties of the activated carbon; however,  
concentrations exceeding the optimal level may  
lead to a decline in adsorption capacity due to the  
saturation of the carbon matrix, which inhibits  
further  
condition was achieved at  
concentration, resulting in  
effective  
activation.  
The  
optimal  
HCl  
maximum Fe  
a
3
N
a
Furthermore, absorptions at 1373, 1308, 523,  
429, 418, and 406 cm¹ correspond to C-H  
bending vibrations of alkanes. These bands are  
adsorption efficiency of 99.14%. The adsorption  
data also followed the Freundlich isotherm  
model more accurately than the Langmuir  
model, as evidenced by a higher regression  
coefficient (R² = 0.9921 for Freundlich compared  
more  
pronounced  
in  
activated  
of  
carbon,  
complex  
suggesting  
the breakdown  
lignocellulosic structures and exposure of  
aliphatic chains after thermal and chemical  
treatment. In non-activated carbon, such peaks  
are typically subdued due to the presence of  
to  
0.9667  
for  
Langmuir),  
surface and  
indicating  
a
heterogeneous  
multilayer  
adsorption process. Furthermore, the activated  
carbon produced under these conditions met the  
requirements of the Indonesian National  
Standard (SNI), with a moisture content of 2.34%,  
ash content of 0.23%, volatile matter content of  
2.05%, bound carbon content of 95.33%, and an  
iodine adsorption capacity of 1116.98 mg/g,  
confirming its high quality and applicability for  
metal ion adsorption in water treatment.  
intact  
macromolecular  
lignin-cellulose  
structures.  
A prominent peak at 1567.12 cm¹ and 1588.44  
cm¹ indicates C=C aromatic stretching,  
highlighting the presence of condensed aromatic  
structures formed during carbonization. These  
peaks are either absent or poorly defined in non-  
activated samples, as the aromatic domains are  
less developed before pyrolysis and activation  
[26].  
Acknowledgement  
The authors are thankfull to Politeknik Negeri  
Sriwijaya,  
which  
has  
facilitated  
the  
implementation of this research.  
Additionally, the peak at 1083.28 cm¹ is  
attributed to CO stretching, characteristic of  
alcohols, ethers, or carboxylic acid groups, often  
enhanced after activation with agents like HCl or  
HPO. Such functional groups are valuable for  
binding polar adsorbates. The corresponding  
peaks at 446 and 418 cm¹ also reinforce the  
presence of C-H bonds in alkane structures. The  
Author Contributions  
Conceptualization, IS, FNA; Methodology, IS ;  
Software, ES ; Validation, ES ; Formal Analysis,  
ASN ; Investigation, ASN ; Resources, FNA ; Data  
Curation, FNA  
;
Writing  
Original Draft  
Preparation, FNA ; Writing Review & Editing,  
SMN ; Visualization, SMN ; Supervision, FNA ;  
comparison  
between  
non-activated  
and  
activated carbon FTIR spectra clearly shows that  
activation significantly enhances the surface  
functionality of kapok banana-derived carbon.  
The activated sample is enriched in hydroxyl,  
aromatic, alkane, and ether/carboxyl groups, all  
of which contribute to its adsorptive efficiency.  
Project  
Administration,  
FNA  
;
Funding  
Acquisition, FNA.  
Conflict of Interest  
The authors declare no conflict of interest.  
Conclusion  
References  
[1]  
Sujiono EH, Zabrian D, Zurnansyah M,  
Mulyati M, Zharva V, Samnur S, Humairah.  
that the concentration of HCl as an activating  
agent significantly influences the quality of  
activated carbon derived from Kepok banana  
stems. Increasing the concentration of HCl  
Fabrication  
Coconut Shell Activated Carbon Using  
Variation Chemical Activation for  
and  
Characterization  
of  
138  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
Wastewater Treatment Application. Result  
in Chemistry. 2022;4, 100291.  
[13] National Standardization Agency. SNI 06-  
3730-1995: Test Method for Ash Content of  
Solid  
Materials  
[Indonesian  
National  
Standard]. BSN 1995.  
[2]  
Haryati S, Yulhan AT, Asparia L. Preparation  
of Activated Carbon from Gelam Bark  
(Melaleuca Leucadendron) Which Originated  
from Tanjung Api-Api South Sumatra.  
Chemical Engineering Journal. 2017;23(2):77-  
Ashari AW & Sitorus S. Effect of Time  
Variation on Xylene Using Activated Carbon  
[14] National Standardization Agency. SNI 06-  
3730-1995: Test method for volatile matter  
content in solid materials [Indonesian  
National Standard]. BSN 1995.  
[15] National Standardization Agency. SNI 06-  
3730-1995: Test method for bound carbon  
content in solid materials [Indonesian  
National Standard]. BSN 1995.  
[16] Kartika SE & Amran MB. Synthesis and  
Characterization of Poly (Anthranilic Acid-  
Co-Formaldehyde) for Adsorption of Pb(II)  
ion. Alchemy. 2021;9(1):15-25.  
[3]  
[4]  
from  
Banana  
Stem  
Waste  
(Musa  
Paradisiaca L). Atomic Journal. 2021;5(2):62-  
66.  
Deepa B, Abraham E, Cherian BM,  
Bismarck  
A,  
Blaker  
JJ,  
Pothan  
LA,  
[17] Syahrir I, Samosir D, Destarini NA, Bariah B.  
Utilization of Banana Stem Waste (Musa  
Paradisiaca L) as Activated Charcoal  
Through Activation Process Using NaOH  
Activator. National Seminar on Research &  
Community Service Results (SNP2M) 2020;  
54-59.  
Kottaisamy M. Structure, Morphology and  
Thermal Characteristics of Banana Nano  
Fibers Obtained by Steam Explosion.  
Bioresource Technology. 2011;102(2):1988-  
1997.  
[5]  
[6]  
Campbell NA, Reece JB. 2008. Biology. 8th  
Ed. Pearson Benjamin Cummings.  
[18] Aryani F. Application of Physical Activation  
and Chemical Activation Methods in the  
Preparation of Activated Charcoal from  
Udyani K, Purwaningsih DY, Setiawan R,  
Yahya K. Preparation of Activated Carbon  
from Mangrove Charcoal using Combined  
Chemical and Physical Activation with  
Coconut  
Shells  
(Cocos  
of  
Nucifera  
L).  
Indonesian  
Journal  
Laboratory.  
Microwave.  
Technology. 2019;23(1):39-46.  
National Standardization Agency. SNI 06-  
3730-1995:Test Method for Moisture  
Content in Solid Materials [indonesian  
national standard]. BSN 1995.  
Journal  
of  
Science  
and  
2019;1(2):16-20.  
[19] Elfia M. Biosorption of Pb(II) Heavy Metal  
Ions using Kepok Banana Stem Biosorbent  
(Musa Acuminata Balbisiana Colla). Clinical  
[7]  
[8]  
Science:  
Journal  
of  
Health  
Analysts.  
2019;7(2):76-82.  
Foo KY & Hameed BH. Insights into The  
Modeling of Adsorption Isotherm Systems.  
Chemical Engineering Journal. 2010;156(1):2-  
10.  
[20] Jankowska H, Swiatkowski A, Choma J.  
1991. Active Carbon. T.J. Kemp, Editor. Ellis  
Horwood Ltd New York.  
[21] Putri RW, Haryati S, Ramatullah R. Effect of  
Carbonation Temperature on the Quality  
of Activated Carbon from Sugarcane  
Bagasse Waste. Journal of Chemical  
Engineering University of Sriwijaya. 2019;  
25(1):1-4.  
[9]  
Metcalf  
&
Eddy.  
2014.  
Wastewater  
Engineering: Treatment and Resource  
Recovery. 5th Ed. Mcgraw-hill education.  
[10] Atkins P & Depaula J. 2010. Physical  
[22] Rowe RC, Sheskey, PJ, Owen SC. 2006.  
Carboxy  
Handbook of Pharmaceutical Excipients.  
Fifth Edition. American Pharmacist  
Methyl  
Cellulose  
Sodium.  
[12] Setianingsih T. 2020. Characterization  
Methods for Carbon Nanomaterials [Metode  
Association Washington, 120122.  
[23] Amehaa B, Nadew TT, Tedla TS, Getye B,  
Karakterisasi  
Karbon  
Nanomaterial].  
Mengie  
DA,  
Ayalneh  
S.  
Universitas Brawijaya Press.  
The Use of Banana Peel as a Low-Cost  
139  
I.Silviyati et al.  
Chempublish Journal, 9(1) 2025,130-140  
Adsorption  
Material  
for  
Removing  
[25] Rahmawati MA, Salam AN, Munte WN,  
Chitraningrum N, and Rahmasari L.  
Synthesis and Characterization Analysis of  
Hexavalent Chromium from Tannery  
Wastewater: Optimization, Kinetic and  
Isotherm Study, and Regeneration Aspects.  
Royal Society of Chemistry. 2024;14(6):3617-  
[24] Chafidz A, Astuti W, Augustia VAS, and  
Rofiah N. Removal of Methyl Violet Dye Via  
Banana  
Peel  
Carbon  
Activated  
as  
Adsorption of Copper (Cu). J. Jurnal Ilmu  
Lingkungan. 2025;23(3):647-657.  
Adsorption  
Prepared from Randu Sawdust (Ceiba  
Pentandra). J. IOP Conference Series:Earth  
using  
Activated  
Carbon  
[26] Cao Y, Zhang J, Yang X, and Shen D.  
Adsorption Behavior of Functional Groups  
in Activated Carbon Derived from Biomass.  
J. Journal of Environmental Chemical  
and  
Environmental  
Science.  
2018;167(1):012013.  
Engineering.  
2020;8(3):103673.  
140